Product ID:PURGEABLE B 1ML, 48852
MSDS Date:02/29/1988
FSC:6850
NIIN:00N019167
MSDS Number: BLGKY

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0.02%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0.02%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

260 MG/M3

RTECS: 9999999ZZ

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.78%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYLENE DICHLORIDE (SARA III)

CAS: 107-06-2

RTECS: KI0525000

Fraction By Weight: 0.02%

OSHA PEL 50 PPM/C,100PPM

ACGIH TLV: 10 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 0.02%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,1,2,2-TETRACHLOROETHANE (SARA III)

CAS: 79-34-5

RTECS: KI8575000

Fraction By Weight: 0.02%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 1 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

TRANS-1,2-DICHLOROETHYLENE ( SEE RTTECS KV9360000 FOR

CAS: 156-60-5

RTECS: KV9400000

Fraction By Weight: 0.02%

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

DICHLOROPROPENE (SARA III)

CAS: 542-75-6

RTECS: UC8310000

Fraction By Weight: 0.04%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 1 PPM; 9192

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BROMOFORM (TRIBROMOMETHANE) (SARA III)

CAS: 75-25-2

RTECS: PB5600000

Fraction By Weight: 0.02%

OSHA PEL S, 0.5 PPM

ACGIH TLV: S, 0.5 PPM; 9192

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

DICHLOROBROMOMETHANE (SARA III)

CAS: 75-27-4

RTECS: PA5310000

Fraction By Weight: 0.02%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50:(ORAL,RAT) 5628 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. HEADACHE, NAUSEA, GI DISTURBANCES, BLINDNESS.
CHLOROCARBON MATERIALS HAVE PRODUCED SENSITIZATION OF THE
MYOCARDIUM TO EPINEPHRINE IN LABORATORY ANIMALS A ND COULD HAVE A
SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:DICHLOROETHANE: CLASS 2 (NTP); CLASS 2B
(IARC). BENZENE: CLASS 1 (NTP/IARC); OSHA REGULATED.
Effects of Overexposure:HLTH HAZ: EXCEPT FOR LIFE-SUSTAINING USES IN
HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN. CONTACT MD. SKIN:
FLUSH WITH LARGE VOLUMES OF WATER. INHAL: IMMED MOVE TO FRESH AIR.
IF BREATHING STOPS, GIVE ARTF RESP. CONTACT MD. INGEST: NEVER GIVE
ANYT HING BY MOUTH TO UNCONSCIOUS PERSON. NEVER TRY TO MAKE AN
UNCONSCIOUS PERSON VOMIT. PRESS FINGERS TO BACK OF TONGUE TO INDUCE
VOMIT. IMMED CONTACT MD. GIVE 2 TBSP OF BAKING SODA IN GLASS OF
WATER.

Flash Point:50.0F,10.0C
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE .

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES.
Other Precautions:AVOID EYE/SKIN CONTACT. AVOID BREATHING VAPORS. NO
SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC
WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY
CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FULL FACE ORGANIC VAPOR
CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:WEAR RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NOT APPLICABLE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:F3
Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.790C
Evaporation Rate & Reference:>1 (ETHER = 1)
Solubility in Water:100%
Appearance and Odor:COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:HCL, PHOSGENE .

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.